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A device for use with a detection means and a solvent source for sampling low volatility hazardous chemicals within a sample matrix is comprised of a sonicator having a probe for providing mechanical agitation to the sample matrix; means for transporting solvent gas from the solvent source to the sample matrix; means for transporting sample gas from the sample matrix to the detection means; and a heating element for heating the sample gas, solvent gas, and sample matrix. The device may include a thermocouple for providing a temperature reading. It also may include a plurality of interchangeable probe tips of different shapes.