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A chemical agent detection system is provided that includes a fluid sampling collector suitable for the collecting, concentrating, filtering and storing of chemical agents. Preferably a solid phase extraction syringe is coupled to an adaptor via an injection port. The adaptor forms an outer surface of a sample containment reservoir that allows the fluid sampling collector to associate with a chemical agent detector such as the M256A2 chemical agent detector. The inventive chemical agent detection system allows rapid, low level on-site detection of chemical agents such as nerve agents in fluid media.